To add or remove users from a Group firstly navigate to the relevant group (Site Actions > Site Settings > People and Groups > yourGroup ). Then in the group page, click the New dropdown and select Add Users:
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This opens the Add Users page (below) where you can either add users by entering them in the Users/Groups box (names should be separated by a semicolon) or click the address book to search and select users from the directory. After you have selected the users to add, either select the group to which you wish to add them or give the users direct permissions. The latter option is not recommended as it will make subsequent administration more difficult since each user’s permissions will have to been updated separately in future.
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